QuEChERS Method for Determination of Some Chlorinated Hydrocarbon and Synthetic Pyrethroid Residues in Sheep Meat by Gas Chromatography-Electron Capture Detector 282
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Author:M. Paramasivam, R. Harischandra Naik and S. Chandrasekaran
p-ISSN:0024-9602, e-ISSN:2582-5321, Vol:98, Issue:jul-sep
DOI: https://doi.org/10.29321/MAJ.10.100298
Abstract
A rapid, simple and efficient multiresidue method was developed and optimized for the
identification and quantification of organochlorine pesticides (OCP) and synthetic pyrethroids
(SPs) in sheep meat samples. The method consists of a modified Quick, Easy, Cheap, Effective,
Rugged, and Safe (QuEChERS) sample preparation method. Samples were extracted with
acetonitrile, and the extracts were cleaned up by dispersive solid phase extraction with
primary secondary amine (PSA) sorbent and anhydrous magnesium sulphate. Determination
and quantification of OCP residues was carried out using a GC-ECD. Mean recoveries were
found in the ranges 70-110 % and 84-99 % for the investigated OCPs and SPs, respectively, with
the RSD was less than 20%. This method was found more efficient and reliable enabling more
number of samples to be analysed in less time. Moreover lipid removal was achieved to a
large extent to get desired result.
Key words : QuEChERS, Multiresidue analysis, Sheep meat, Chlorinated hydrocarbons, Synthetic
pyrethroids, GC-ECD.
